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Potassium dichromate solution

for 1000 ml, c(K₂Cr₂O₇) = 1/₆₀ mol/l (0.1 N) Titrisol®
Code: 1099280001
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for 1000 ml, c(K₂Cr₂O₇) = 1/₆₀ mol/l (0.1 N) Titrisol®
Replacement Information
Replacement Information In North America 109928.0001 is an alternative to PX1443-6, can be easily and conveniently made up to same volume and strength
Description
Catalogue Number 109928
Replaces PX1443-6
Product Information
HS Code 2841 50 00
Physicochemical Information
Density 1.06 g/cm3 (20 °C)
pH value 4.1 (H₂O, 20 °C)
Safety Information according to GHS
Hazard Pictogram(s)


Hazard Statement(s) H340: May cause genetic defects.
H350: May cause cancer.
H360FD: May damage fertility. May damage the unborn child.
H302: Harmful if swallowed.
H314: Causes severe skin burns and eye damage.
H317: May cause an allergic skin reaction.
H331: Toxic if inhaled.
H334: May cause allergy or asthma symptoms or breathing difficulties if inhaled.
H335: May cause respiratory irritation.
H373: May cause damage to organs through prolonged or repeated exposure.
H411: Toxic to aquatic life with long lasting effects.
Precautionary Statement(s) P201: Obtain special instructions before use.
P273: Avoid release to the environment.
P280: Wear protective gloves/ protective clothing/ eye protection/ face protection.
P301 + P330 + P331: IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.
P302 + P352: IF ON SKIN: Wash with plenty of soap and water.
P304 + P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P308 + P310: IF exposed or concerned: immediately call a POISON CENTER or doctor/ physician.
Storage class 6.1 D Non combustible, acute toxicity cat. 3 / toxic or substances with chronic effects
WGK WGK 3 highly water endangering
Disposal 22
Inorganic peroxides and oxidants as well as bromine and iodine should be rendered harmless by reduction with acidic sodium thiosulfate solution (Cat. No. 106513); container D or E. Slightly soluble oxidants should be collected separately in container E or I.
Safety Information
Hazard Symbols Toxic
Dangerous for the environment
Categories of danger carcinogenic, mutagenic, toxic for reproduction, toxic, irritant, sensitizing, dangerous for the environment
R Phrase R 45-46-60-61-22-23-48/20-36/37/38-42/43-51/53
May cause cancer.May cause heritable genetic damage.May impair fertility.May cause harm to the unborn child.Also harmful if swallowed.Also toxic by inhalation.Also harmful: danger of serious damage to health by prolonged exposure through inhalation.Irritating to eyes, respiratory system and skin.May cause sensitisation by inhalation and skin contact.Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
S Phrase S 53-17-23-24-37-45-61
Avoid exposure - obtain special instructions before use.Keep away from combustible material.Do not breathe vapour.Avoid contact with skin.Wear suitable gloves.In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible).Avoid release to the environment. Refer to special instructions/ Safety data sheets.
Storage and Shipping Information
Storage Store at +15°C to +25°C.
Transport Information
Declaration (railroad and road) ADR, RID UN 3287 , 6.1, III
Declaration (transport by air) IATA-DGR UN 3287 , 6.1, III
Declaration (transport by sea) IMDG-Code UN 3287 , 6.1, III
Specifications
Concentration after dilution to 1 liter: c(K₂Cr₂O₇) = 1/60 mol/l
Amount-of-substance concentration 1/60 mol/l
The concentration of this solution was determined with sodium thiosulfate standard solution (article number 1.09147) standardized against volumetric standard potassium iodate (article number 1.02404). The determined titer at 20°C was 1.000 with an expanded measurement uncertainty of ± 0.004 (k=2 coverage factor for 95% coverage probability). The certified value is traceable to primary standard NIST SRM 136f (NIST: National Institute of Standards and Technology, USA) by means of volumetric standard potassium iodate, measured in the accredited calibration laboratory of Merck KGaA, Darmstadt, Germany in accordance to DIN EN ISO/IEC 17025.
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