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Methyl formate

Methyl formate for synthesis. CAS 107-31-3, pH 4 - 5 (200 g/l, H₂O, 20 °C). MSDS and product info below.
Code: 8008891000
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Methyl formate for synthesis. CAS 107-31-3, pH 4 - 5 (200 g/l, H₂O, 20 °C). MSDS and product info below.

Key Spec Table

CAS #EC NumberHill FormulaMolar Mass
107-31-3 203-481-7 C₂H₄O₂ 60.05 g/mol
Description
Catalogue Number 800889
Synonyms Formic acid methyl ester
Product Information
CAS number 107-31-3
EC index number 607-014-00-1
EC number 203-481-7
Hill Formula C₂H₄O₂
Molar Mass 60.05 g/mol
HS Code 2915 13 00
Structure formula Image
Applications
Application Methyl formate for synthesis. CAS 107-31-3, pH 4 - 5 (200 g/l, H₂O, 20 °C). MSDS and product info below.
Physicochemical Information
Boiling point 31.5 °C (1013 hPa)
Density 0.968 g/cm3 (20 °C)
Explosion limit 5 - 23 %(V)
Flash point -32 °C
Ignition temperature 450 °C
Melting Point -100.4 °C
pH value 4 - 5 (200 g/l, H₂O, 20 °C)
Vapor pressure 644 hPa (20 °C)
Solubility 300 g/l
Toxicological Information
LD 50 oral LD50 Rat 1500 mg/kg
LD 50 dermal LD50 Rat > 4000 mg/kg
Safety Information according to GHS
Hazard Pictogram(s)
Hazard Statement(s) H224: Extremely flammable liquid and vapour.
H302 + H332: Harmful if swallowed or if inhaled
H319: Causes serious eye irritation.
H335: May cause respiratory irritation.
Precautionary Statement(s) P210: Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.
P240: Ground/bond container and receiving equipment.
P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P403 + P233: Store in a well-ventilated place. Keep container tightly closed.
RTECS LQ8925000
Storage class 3 Flammable liquids
WGK WGK 1 slightly water endangering
Disposal 3
Relatively unreactive organic reagents should be collected in container A. If halogenated, they should be collected in container B. For solid residues use container C.
Safety Information
Hazard Symbols Highly Flammable
Harmful
Categories of danger extremely flammable, harmful, irritant
R Phrase R 12-20/22-36/37
Extremely flammable.Harmful by inhalation and if swallowed.Irritating to eyes and respiratory system.
S Phrase S 3- 9-16
Keep in a cool place.Keep container in a well-ventilated place.Keep away from sources of ignition - No smoking.
Storage and Shipping Information
Storage Store below +30°C.
Transport Information
Declaration (railroad and road) ADR, RID UN 1243 , 3, I
Declaration (transport by air) IATA-DGR UN 1243 , 3, I
Declaration (transport by sea) IMDG-Code UN 1243 , 3, I
Specifications
Assay (GC, area%) 95.0 - 97.0 % (a/a)
Density (d 20 °C/ 4 °C) 0.967 - 0.971
Methanol (GC, area%) 3.0 - 5.0 % (a/a)
Identity (IR) passes test
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